The Art of Perfumery by George William Septimus Piesse (english readers .TXT) 📕

many cases, from making an accurate analysis of them. The largest samples were those of a compound labelled "pear-oil," which, by analysis, I discovered to be an alcoholic solution of pure acetate of amyloxide. Not having sufficient quantity to purify it for combustion, I dissolved it with potash, by which free fusel-oil was separated, and determined the acetic acid in the form of a silver salt.

0.3080 gram. of silver salt = 0.1997 gram. of silver.

The per centage of silver in acetate of silver is, according to

Theory,          64.68
Experiment,      64.55

The acetate of amyloxide, which, according to the usual way of preparing it, represents one part sulphuric acid, one part fusel-oil, and two parts of acetate of potash, had a striking smell of fruit, but it acquired the pleasant flavor of the jargonelle pear only after having been diluted with six times its volume of spirit of wine.

Upon further inquiry I learned that considerable quantities of this oil are manufactured by some distillers,—from fifteen to twenty pounds weekly,—and sold to confectioners, who employ it chiefly in flavoring pear-drops, which are nothing else but barley-sugar, flavored with this oil.

I found, besides the pear-oil, also an apple-oil, which, according to my analysis, is nothing but valerianate of amyloxide. Every one must recollect the insupportable smell of rotten apples which fills the laboratory whilst making valerianic acid. By operating upon this raw distillate produced with diluted potash, valerianic acid is removed, and an ether remains behind, which, diluted in five or six times its volume of spirits of wine, is possessed of the most pleasant flavor of apples.

The essential oil[L] most abundant in the Exhibition was the pine-apple oil, which, as you well know, is nothing else but the butyrate of ethyloxide. Even in this combination, like in the former, the pleasant flavor or scent is only attained by diluting the ether with alcohol. The butyric ether which is employed in Germany to flavor bad rum, is employed in England to flavor an acidulated drink called pine-apple ale. For this purpose they generally do not employ pure butyric acid, but a product obtained by saponification of butter, and subsequent distillation of the soap with concentrated sulphuric acid and alcohol; which product contains, besides the butyric ether, other ethers, but nevertheless can be used for flavoring spirits. The sample I analyzed was purer, and appeared to have been made with pure butyric ether.

Decomposed with potash and changed into silver salt, it gave

0.4404 gram. of silver salt = 0.2437 gram. of silver.

The per centage of silver in the butyrate of silver is according to

Theory, 55.38
Experiment, 55.33

Both English and French exhibitors have also sent samples of cognac-oil and grape-oil, which are employed to flavor the common sorts of brandy. As these samples were very small, I was prevented from making an accurate analysis. However, I am certain that the grape-oil is a combination of amyl, diluted with much alcohol; since, when acted upon with concentrated sulphuric acid, and the oil freed from alcohol by washing it with water, it gave amylsulphuric acid, which was identified by the analysis of the salt of barytes.

1.2690 gram. of amylsulphate of barytes gave 0.5825 gram. of sulphate of barytes. This corresponds to 45.82 per cent. of sulphate of barytes.

Amylsulphate of barytes, crystallized with two equivalents of water, contains, according to the analysis of Cahours and Kekule, 45.95 per cent. of sulphate of barytes. It is curious to find here a body, which, on account of its noxious smell, is removed with great care from spirituous liquors, to be applied under a different form for the purpose of imparting to them a pleasant flavor.

I must needs here also mention the artificial oil of bitter almonds. When Mitscherlich, in the year 1834, discovered the nitrobenzol, he would not have dreamed that this product would be manufactured for the purpose of perfumery, and, after twenty years, appear in fine labelled samples at the London Exhibition. It is true that, even at the time of the discovery of nitrobenzol, he pointed out the striking similarity of its smell to that of the oil of bitter almonds. However, at that time, the only known sources for obtaining this body were the compressed gases and the distillation of benzoic acid, consequently the enormity of its price banished any idea of employing benzol as a substitute for oil of bitter almonds. However, in the year 1845, I succeeded by means of the anilin-reaction in ascertaining the existence of benzol in common coal-tar oil; and, in the year 1849, C.B. Mansfield proved, by careful experiments, that benzol can be won without difficulty in great quantity from coal-tar oil. In his essay, which contains many interesting details about the practical use of benzol, he speaks likewise of the possibility of soon obtaining the sweet-scented nitrobenzol in great quantity. The Exhibition has proved that his observation has not been left unnoticed by the perfumers. Among French perfumeries we have found, under the name of artificial oil of bitter almonds, and under the still more poetical name of "essence de mirbane," several samples of essential oils, which are no more nor less than nitrobenzol. I was not able to obtain accurate details about the extent of this branch of manufacture, which seems to be of some importance. In London, this article is manufactured with success. The apparatus employed is that of Mansfield, which is very simple. It consists of a large glass worm, the upper extremity of which divides in two branches or tubes, which are provided with funnels. Through one of these funnels passes a stream of concentrated nitric acid; the other is destined as a receiver of benzol, which, for this purpose, requires not to be quite pure; at the angle from where the two tubes branch out, the two bodies meet together, and instantly the chemical combination takes place, which cools sufficiently by passing through the glass worm. The product is afterwards washed with water, and some diluted solution of carbonate of soda; it is then ready for use. Notwithstanding the great physical similarity between nitrobenzol and oil of bitter almonds, there is yet a slight difference in smell which can be detected by an experienced nose.[M] However, nitrobenzol is very useful in scenting soap, and might be employed with great advantage by confectioners and cooks, particularly on account of its safety, being entirely free from prussic acid.

There were, besides the above, several other artificial oils; they all, however, were more or less complicated, and in so small quantities, that it was impossible to ascertain their exact nature, and it was doubtful whether they had the same origin as the former.

The application of organic chemistry to perfumery is quite new; it is probable that the study of all the ethers or ethereal combinations already known, and of those which the ingenuity of the chemist is daily discovering, will enlarge the sphere of their practical applications. The capryl-ethers lately discovered by Bouis are remarkable for their aromatic smells (the acetate of capryloxide is possessed of the most intense and pleasant smell), and they promise a large harvest to the manufacturers of perfumes.—Annalen der Chemie.

CORRESPONDENCE FROM THE "JOURNAL OF THE SOCIETY OF ARTS."[N] Chemistry and Perfumery.

Sir,

When such periodicals as "Household Words" and the "Family Herald" contain scientific matters, treated in a manner to popularize science, all real lovers of philosophy must feel gratified; a little fiction, a little metaphor, is expected, and is accepted with the good intention with which it is given, in such popular prints; but when the "Journal of the Society of Arts" reprints quotations from such sources, without modifying or correcting their expressions, it conveys to its readers a tissue of fiction rather too flimsy to bear a truthful analysis.[O]

In the article on Chemistry and Perfumery, in No. 47, you quote that "some of the most delicate perfumes are now made by chemical artifice, and not, as of old, by distilling them from flowers." Now, sir, this statement conveys to the public a very erroneous idea; because the substances afterwards spoken of are named essences of fruit, and not essences of flowers, and the essences of fruits named in your article never are, and never can be, used in perfumery. This assertion is based on practical experience. The artificial essences of fruits are ethers: when poured upon a handkerchief, and held up to the nose, they act, as is well known, like chloroform. Dare a perfumer sell a bottle of such a preparation to an "unprotected female?"

Again, you quote that "the drainings of cow-houses are the main source to which the manufacturer applies for the production of his most delicate and admired perfumes."

Shade of Munchausen! must I refute this by calling your attention to the fact that in the south of France more than 80,000 persons are employed, directly and indirectly, in the cultivation of flowers, and in the extraction of their odors for the use of perfumers? that Italy cultivates flowers for the same purpose to an extent employing land as extensive as the whole of some English counties? that tracts of flower-farms exist in the Balkan, in Turkey, more extensive than the whole of Yorkshire? Our own flower-farms at Mitcham, in Surrey, need not be mentioned in comparison, although important. These, sir, are the main sources of perfumes. There are other sources at Thibet, Tonquin, and in the West Indies; but enough has been said, I hope, to refute the cow-house story. This story is founded on the fact that Benzoic acid can be obtained from the draining of stables, and that Benzoic acid has rather a pleasant odor. Some of the largest wholesale perfumers use five or six pounds of gum benzoin per annum, but none use the benzoic acid. The lozenge-makers consume the most of this article when prepared for commercial purposes; as also the fruit essences. Those of your readers interested in what really is used in perfumery, are referred to the last six numbers of the "Annals of Pharmacy and Practical Chemistry," article "Perfumery."